Record:   Prev Next
Author Davies, P R
Title Atom Resolved Surface Reactions : Nanocatalysis
Imprint Cambridge : Royal Society of Chemistry, 2007
©2008
book jacket
Edition 1st ed
Descript 1 online resource (240 pages)
text txt rdacontent
computer c rdamedia
online resource cr rdacarrier
Series ISSN ; v.4
ISSN
Note Atom Resolved Surface Reactions -- Contents -- Abbreviations -- Some Relevant Units - SI and Derived Units -- CHAPTER 1 Some Milestones in the Development of Surface Chemistry and Catalysis -- 1.1 Introduction -- 1.2 1926: Catalysis Theory and Practice -- Rideal and Taylor -- 1.3 1932: Adsorption of Gases by Solids -- Faraday Discussion, Oxford -- 1.4 1940: Seventeenth Faraday Lecture -- Langmuir -- 1.5 1950: Heterogeneous Catalysis -- Faraday Discussion, Liverpool -- 1.6 1954: Properties of Surfaces -- 1.7 1957: Advances in Catalysis -- International Congress on Catalysis, Philadelphia -- 1.8 1963: Conference on Clean Surfaces with Supplement: Surface Phenomena in Semiconductors, New York -- 1.9 1966: Faraday Discussion Meeting, Liverpool -- 1.10 1967: The Emergence of Photoelectron Spectroscopy -- 1.11 1968: Berkeley Meeting: Structure and Chemistry of Solid Surfaces -- 1.12 1972: A Discussion on the Physics and Chemistry of Surfaces, London -- 1.13 1987: Faraday Symposium, Bath -- 1.14 Summary -- References -- Further Reading -- CHAPTER 2 Experimental Methods in Surface Science Relevant to STM -- 2.1 Introduction -- 2.2 Kinetic Methods -- 2.3 Vibrational Spectroscopy -- 2.4 Work Function -- 2.5 Structural Studies -- 2.6 Photoelectron Spectroscopy -- 2.7 The Dynamics of Adsorption -- 2.8 Summary -- References -- Further Reading -- CHAPTER 3 Scanning Tunnelling Microscopy: Theory and Experiment -- 3.1 The Development of Ultramicroscopy -- 3.2 The Theory of STM -- 3.3 The Interpretation of STM Images -- 3.4 Scanning Tunnelling Spectroscopy -- 3.5 The STM Experiment -- 3.6 The Scanner -- 3.6.1 Sample Approach -- 3.6.2 Adaptations of the Scanner for Specific Experiments -- 3.7 Making STM Tips -- 3.7.1 Tip Materials -- References -- CHAPTER 4 Dynamics of Surface Reactions and Oxygen Chemisorption -- 4.1 Introduction
4.2 Surface Reconstruction and ''Oxide'' Formation -- 4.3 Oxygen States at Metal Surfaces -- 4.4 Control of Oxygen States by Coadsorbates -- 4.5 Adsorbate Interactions, Mobility and Residence Times -- 4.6 Atom-tracking STM -- 4.7 Hot Oxygen Adatoms: How are they Formed? -- 4.8 Summary -- References -- Further Reading -- CHAPTER 5 Catalytic Oxidation at Metal Surfaces: Atom Resolved Evidence -- 5.1 Introduction -- 5.2 Ammonia Oxidation -- 5.2.1 Cu(110) Pre-exposed to Oxygen -- 5.2.2 Coadsorption of Ammonia-Oxygen Mixtures at Cu(110) -- 5.2.3 Coadsorption of Ammonia-Oxygen Mixtures at Mg(0001) -- 5.2.4 Ni(110) Pre-exposed to Oxygen -- 5.2.5 Ag(110) Pre-exposed to Oxygen -- 5.3 Oxidation of Carbon Monoxide -- 5.4 Oxidation of Hydrogen -- 5.5 Oxidation of Hydrocarbons -- 5.6 Oxidation of Hydrogen Sulfide and Sulfur Dioxide -- 5.7 Theoretical Analysis of Activation by Oxygen -- 5.8 Summary -- References -- Further Reading -- CHAPTER 6 Surface Modification by Alkali Metals -- 6.1 Introduction -- 6.2 Infrared Studies of CO at Cu(110)-Cs -- 6.3 Structural Studies of the Alkali Metal-modified Cu(110) Surface -- 6.3.1 Low-energy Electron Diffraction -- 6.3.2 Scanning Tunnelling Microscopy -- 6.3.3 Cu(110)-Cs System -- 6.3.4 Oxygen Chemisorption at Cu(110)-Cs -- 6.4 Reactivity of Cu(110)-Cs to NH3 and CO2 -- 6.5 Au(110)-K System -- 6.6 Cu(100)-Li System -- 6.7 Summary -- References -- Further Reading -- CHAPTER 7 STM at High Pressure -- 7.1 Introduction -- 7.2 Catalysis and Chemisorption at Metals at High Pressure -- 7.2.1 Carbon Monoxide and Nitric Oxide -- 7.2.2 Hydrogenation of Olefins -- 7.3 Restructuring of the Pt(110)-(1 × 2) Surface by Carbon Monoxide -- 7.4 Adsorption-induced Step Formation -- 7.5 Gold Particles at FeO(111) -- 7.6 Hydrogen-Deuterium Exchange and Surface Poisoning -- 7.7 Summary -- References -- Further Reading
CHAPTER 8 Molecular and Dissociated States of Molecules: Biphasic Systems -- 8.1 Introduction -- 8.2 Nitric Oxide -- 8.3 Nitrogen Adatoms: Surface Structure -- 8.4 Carbon Monoxide -- 8.5 Hydrogen -- 8.6 Dissociative Chemisorption of HCl at Cu(110) -- 8.7 Chlorobenzene -- 8.8 Hydrocarbon Dissociation: Carbide Formation -- 8.9 Dissociative Chemisorption of Phenyl Iodide -- 8.10 Chemisorption and Trimerisation of Acetylene at Pd(111) -- 8.11 Summary -- References -- Further Reading -- CHAPTER 9 Nanoparticles and Chemical Reactivity -- 9.1 Introduction -- 9.2 Controlling Cluster Size on Surfaces -- 9.3 Alloy Ensembles -- 9.4 Nanoclusters at Oxide Surfaces -- 9.5 Oxidation and Polymerisation at Pd Atoms Deposited on MgO Surfaces -- 9.6 Clusters in Nanocatalysis -- 9.7 Molybdenum Sulfide Nanoclusters and Catalytic Hydrodesulfurisation Reaction Pathways -- 9.8 Nanoparticle Geometry at Oxide-supported Metal Catalysts -- 9.9 Summary -- References -- Further Reading -- CHAPTER 10 Studies of Sulfur and Thiols at Metal Surfaces -- 10.1 Introduction -- 10.2 Studies of Atomic Sulfur Adsorbed at Metal Surfaces -- 10.2.1 Copper -- 10.2.2 Nickel -- 10.2.3 Gold and Silver -- 10.2.4 Platinum, Rhodium, Ruthenium and Rhenium -- 10.2.5 Alloy Systems -- 10.3 Sulfur-containing Molecules -- 10.4 Summary -- References -- Further Reading -- CHAPTER 11 Surface Engineering at the Nanoscale -- 11.1 Introduction -- 11.2 ''Bottom-up'' Surface Engineering -- 11.2.1 Van der Waals Forces -- 11.2.2 Hydrogen Bonding -- 11.2.3 Chiral Surfaces from Prochiral Adsorbates -- 11.2.4 Covalently Bonded Systems -- 11.3 Surface Engineering Using Diblock Copolymer Templates -- 11.4 Summary -- References -- Further Reading -- Epilogue -- Subject Index
This book offers a unique perspective of the impact of scanning probe microscopies on our understanding of the surface chemistry at the nanoscale
Description based on publisher supplied metadata and other sources
Electronic reproduction. Ann Arbor, Michigan : ProQuest Ebook Central, 2020. Available via World Wide Web. Access may be limited to ProQuest Ebook Central affiliated libraries
Link Print version: Davies, P R Atom Resolved Surface Reactions : Nanocatalysis Cambridge : Royal Society of Chemistry,c2007 9780854042692
Subject Surface chemistry.;Nanochemistry.;Chemical reactions
Electronic books
Alt Author Roberts, M W
O'Brien, Paul
Kroto, Harry
Craighead, Harold
Record:   Prev Next