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050  4 QD181.C6 .C384 2013 
082 0  546.6 
100 1  Cao, Gang 
245 10 Frontiers Of 4d- And 5d-transition Metal Oxides 
264  1 Singapore :|bWorld Scientific Publishing Company,|c2013 
264  4 |c©2013 
300    1 online resource (328 pages) 
336    text|btxt|2rdacontent 
337    computer|bc|2rdamedia 
338    online resource|bcr|2rdacarrier 
505 0  Intro -- CONTENTS -- Preface -- Chapter 1 Introduction 
       Gang Cao and Lance E. DeLong -- Chapter 2 Spectroscopic 
       Studies of Strong Spin-Orbit Coupling in 4d and 5d 
       Transition Metal Oxides Soon Jae Moon and Tae Won Noh -- 
       2.1. Introduction -- 2.2. Spin-orbit Coupling-induced 
       Fermi Surface Modification in 4d Sr2RuO4 and Sr2RhO4 -- 
       2.3. Spin-orbit Coupling-induced Jeff = 1/2 Mott State of 
       5d Sr2IrO4 -- 2.3.1. Theoretical Description of the Jeff =
       1/2 Mott State of Sr2IrO4 -- 2.3.1.1. Schematic Model for 
       the Jeff = 1/2 Mott State in the Atomic Limit -- 2.3.1.2. 
       Density-functional-theory Calculations -- 2.3.2. 
       Spectroscopic Studies of the Jeff = 1/2 Mott State in 
       Sr2IrO4 -- 2.3.2.1. Optical Spectroscopy -- 2.3.2.2. Angle
       -Resolved Photoemission Spectroscopy -- 2.3.2.3. X-ray 
       Absorption Spectroscopy -- 2.3.2.4. Resonant X-ray 
       Scattering -- 2.3.3. Temperature-dependence of the 
       Electronic Structure of the Jeff = 1/2 Mott State -- 2.4. 
       Correlated Metallic State of 5d Iridates -- 2.4.1. 
       Dimensionality-controlled Insulator-Metal Transition in 
       Ruddlesden-Popper Series Srn+1IrnO3n+1 (n = 1, 2, and  ) -
       - 2.4.2. Electronic Structure Evolution in the Bandwidth-
       controlled Ca1-xSrxIrO3 System -- 2.5. Roles of Spin-orbit
       Coupling in Double Perovskite Rhenates and Other Iridates 
       -- 2.5.1. Double perovskite A2FeReO6 (A = Ba, Ca) -- 
       2.5.2. Large Orbital Magnetism and Spin-orbit Effects in 
       BaIrO3 -- 2.5.3. Pyrochlore Iridates R2Ir2O7 (R: rare 
       earth ions) -- 2.6. Future Studies -- Acknowledgments -- 
       References -- Chapter 3 X-Ray Scattering Studies of 4d- 
       and 5d-Electron Transition Metal Oxides Ioannis 
       Zegkinoglou and Bernhard Keimer -- 3.1. Introduction -- 
       3.2. Non-Resonant X-Ray Scattering -- 3.3. Resonant X-Ray 
       Diffraction -- 3.3.1. Basic Principles and Historical 
       Background -- 3.3.2. Resonant Electric Dipole Scattering 
       Length -- 3.4. Orbital Ordering in Ca2RuO4 
505 8  3.4.1. Introduction -- 3.4.2. Main Properties -- 3.4.3. 
       Orbital Order -- 3.4.4. X-Ray Investigations -- 3.5. Spin 
       Reorientation in Ca3Ru2O7 -- 3.5.1. Introduction -- 3.5.2.
       Main Properties -- 3.5.3. X-Ray Investigations -- 3.6. 
       Magnetic Structure Determination in RuSr2GdCu2O8 -- 3.6.1.
       Introduction -- 3.6.2. Main Properties -- 3.6.3. X-Ray 
       Investigations -- 3.7. Spin Orbital Mott State in Sr2IrO4 
       -- 3.7.1. Introduction -- 3.7.2. Main Properties -- 3.7.3.
       X-Ray Investigations -- References -- Chapter 4 Exploring 
       the Magnetostructural Phases of the Layered Ruthenates 
       with Raman Scattering S. L. Cooper -- 4.1. Introduction-
       Overview of the Layered Ruthenate Materials -- 4.2. Raman 
       Scattering as a Probe of Correlated Materials -- 4.2.1. 
       General Raman Scattering Details -- 4.2.2. Raman 
       Scattering Cross Section -- 4.2.2.1. Phonon Raman 
       Scattering -- 4.2.2.2. Magnon Raman Scattering -- 4.3. 
       Experimental Details -- 4.3.1. Raman Scattering System -- 
       4.3.2. High Magnetic Field Measurements -- 4.3.3. High 
       Pressure Measurements -- 4.4. Raman Scattering Studies of 
       Single-Layer (Ca,Sr)2RuO4 -- 4.4.1. Overview -- 4.4.1.1. 
       Temperature-Dependent Effects in Ca2RuO4 -- 4.4.1.2. 
       Doping Dependence of (Ca,Sr)2RuO4 -- 4.4.2. Phonon and 
       Magnon Scattering in Ca2RuO4 -- 4.4.3. Franck-Condon 
       Effects in the Orbital-Ordered Phase of Ca2RuO4 -- 4.4.4. 
       Doping Dependence of Magnon and Phonon Scattering in (Ca,
       Sr)2RuO4 -- 4.4.5. Pressure Dependence of Magnon 
       Scattering in Ca2RuO4 -- 4.5. Raman Scattering in Ca3Ru2O7
       -- 4.5.1. Overview -- 4.5.2. Magnon and Phonon Scattering 
       in Ca3Ru2O7 -- 4.5.2.1. Magnetic Phases in Ca3Ru2O7: 
       Magnon Scattering -- 4.5.2.2. Structural/Orbital Phases in
       Ca3Ru2O7: Octahedral Phonon Scattering -- 4.5.3. 
       Temperature-Dependent Structural/Orbital Phases in 
       Ca3Ru2O7 -- 4.5.3.1. High-Conducting, Orbital-Degenerate 
       Regime 
505 8  4.5.3.2. Low-Conducting, Orbital-Polarized Regime -- 
       4.5.4. Field-Dependent Structural/Orbital Phases in 
       Ca3Ru2O7 -- 4.5.4.1. Structural/Orbital Phases in Ca3Ru2O7
       for H Magnetic Easy-Axis -- 4.5.4.2. Structural/Orbital 
       Phases in Ca3Ru2O7 for H//Magnetic Easy-Axis -- 4.5.5. 
       Pressure-Dependent Structural/Orbital Phases in Ca3Ru2O7 -
       - 4.6. Raman Scattering in Triple-Layer Sr4Ru3O10 -- 
       4.6.1. Overview -- 4.6.2. T-Dependent Phonon Spectrum and 
       Spin-Phonon Coupling in Sr4Ru3O10 -- 4.6.3. Field-
       Dependent Phonon Spectrum of Sr4Ru3O10 -- 4.6.3.1. Field-
       Dependent Phonon Spectrum, H//c-axis -- 4.6.3.2. Field-
       Dependent Phonon Spectrum, H//ab-plane -- 4.6.4. Pressure-
       Dependent Phonon Spectrum of Sr4Ru3O10 -- 4.7. Summary -- 
       Acknowledgments -- References -- Chapter 5 Metal-Insulator
       Transitions in n = 1 Ruddlesden-Popper Ruthenates Rongying
       Jin -- 5.1. Introduction -- 5.2. Single-Layered A2RuO4 
       with A = Ca, Sr, Ba -- 5.3. Chemical Doping Effect on the 
       Metal-Insulator Transition -- 5.3.1. Ca2-xA' xRuO4 (A' = 
       Sr, La, Y) -- 5.3.2. Sr2Ru1-xTxO4 (T = Ti, Mn, Fe, Mo, Ir)
       -- 5.4. Summary and Outlook -- Acknowledgments -- 
       References -- Chapter 6 The Contradictory Physical 
       Properties and Extreme Anisotropy of Ca3Ru2O7 G. Cao, L. 
       E. DeLong and P. Schlottmann -- 6.1. Introduction -- 6.2. 
       Some Underlying Properties of Ca3Ru2O7 -- 6.3. Single 
       Crystal Growth and Characterization -- 6.4. Results and 
       Discussion -- 6.4.1. Colossal Magnetoresistance via 
       Suppression of a Ferromagnetic State -- 6.4.2. Bulk Spin 
       Valve Effect -- 6.4.2.1. High-Field Stability of the 
       Antiferromagnetic Metallic State -- 6.4.2.2. Anomalous 
       Anisotropy of Magnetic and Magnetotransport Properties -- 
       6.4.2.3. The Bulk Spin Valve Scenario -- 6.4.3. 
       Oscillatory Magnetoresistance Periodic in 1/B and B -- 
       6.4.3.1. Shubnikov-deHaas Effect for B // c -- 6.4.3.2. 
       Shubnikov-deHaas Effect in the bc-Plane 
505 8  6.4.3.3. Magnetoresistance Oscillations Periodic in B -- 
       6.5. Conclusions -- Acknowledgements -- References -- 
       Chapter 7 Surfaces of Transition-Metal Compounds: The 
       Interplay Between Structure and Functionality Xiaobo He, 
       Jing Teng, Von Braun Nascimento, R. G. Moore, Guorong Li, 
       Chen Chen, Jiandi Zhang and E. W. Plummer -- 7.1. 
       Introduction -- 7.2. Surface Structural Techniques -- 
       7.2.1. Glazing Incidence X-ray Diffraction -- 7.2.2. 
       Electron Microscopy -- 7.2.3. Low Energy Electron 
       Diffraction -- 7.2.4. Scanning Tunneling Microscopy -- 
       7.3. Examples: The Interplay of Structure and 
       Functionality -- 7.3.1. Single-layered Ruthenate RP Series
       : Ca2-xSrxRuO4 -- 7.3.2. Manganites La2-2xSr1+2xMn2O7(001)
       -- 7.3.3. Iron-based Superconductors -- 7.4. Conclusion --
       Acknowledgments -- References -- Chapter 8 Instability of 
       the Jeff = 1/2 Insulating State in Sr2IrO4 and Sr3Ir2O7 (n
       = 1 and 2) G. Cao and L. E. DeLong -- 8.1. Introduction --
       8.2. Sr2IrO4 -- 8.2.1. Lattice-Driven Magnetoresistivity -
       - 8.2.2. Rh Doping to Tune the Spin-Orbit Interaction -- 
       8.2.3. Metal-Insulator Transition via Electron or Hole 
       Doping -- 8.2.4. Non-Ohmic Behavior -- 8.2.5. Giant 
       Magnetoelectric Effect -- 8.3. Sr3Ir2O7 -- 8.3.1. Unusual 
       Magnetism and Transport Properties -- 8.3.2. Metal-
       Insulator Transition via Electron Doping and Pressure -- 
       8.4. Conclusions -- Acknowledgments -- References -- Index
520    This book is aimed at advanced undergraduates, graduate 
       students and other researchers who possess an introductory
       background in materials physics and/or chemistry, and an 
       interest in the physical and chemical properties of novel 
       materials, especially transition metal oxides.New 
       materials often exhibit novel phenomena of great 
       fundamental and technological importance. Contributing 
       authors review the structural, physical and chemical 
       properties of notable 4d- and 5d-transition metal oxides 
       discovered over the last 10 years. These materials exhibit
       extraordinary physical properties that differ 
       significantly from those of the heavily studied 3d-
       transition metal oxides, mainly due to the relatively 
       strong influence of the spin-orbit interaction and orbital
       order in 4d- and 5d materials. The immense growth in 
       publications addressing the physical properties of these 
       novel materials underlines the need to document recent 
       advances and the current state of this field. This book 
       includes overviews of the current experimental situation 
       concerning these materials 
588    Description based on publisher supplied metadata and other
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590    Electronic reproduction. Ann Arbor, Michigan : ProQuest 
       Ebook Central, 2020. Available via World Wide Web. Access 
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650  0 Transition metal oxides.;Electric insulators and 
       insulation -- Metallic oxides 
655  4 Electronic books 
700 1  Delong, Lance E 
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