Record:   Prev Next
作者 Sevilla, Michael D
書名 Electron Paramagnetic Resonance : Volume 16
出版項 Cambridge : Royal Society of Chemistry, 1998
©1998
國際標準書號 9781847553539 (electronic bk.)
9780854043057
book jacket
版本 1st ed
說明 1 online resource (302 pages)
text txt rdacontent
computer c rdamedia
online resource cr rdacarrier
系列 ISSN
ISSN
附註 ELECTRON PARAMAGNETIC RESONANCE -- Contents -- Chapter 1 Biological Free Radicals -- 1 Introduction and Scope of Review -- 2 Metal Ions -- 2.1 Iron -- 2.2 Copper -- 2.3 Chromium -- 2.4 Other Metal Ions -- 3 Hydroperoxides -- 3.1 Alkyl/Aryl Hydroperoxides -- 3.2 Amino Acid, Protein and Nucleic Acid Hydroperoxides -- 4 Protein-derived Radicals -- 5 Veratyl Alcohol -- 6 Beta-amyloid Protein -- 7 Ozone -- 8 Nitric Oxide -- 9 Peroxynitrite(ONOO‾) -- 10 Asbestos, Mineral Fibres and Diesel Particles -- 11 Cigarette Smoke -- 12 Paraquat -- 13 Halogenated Compounds -- 14 Ethanol -- 15 Retinoic Acid -- 16 Quinones -- 17 Phenols and Related Compounds -- 18 Thiols, Disulfides and Related Compounds -- 19 Ascorbate -- 19.1 Clinical Studies -- 19.2 Animal Studies -- 19.3 In Vitro Studies -- 20 Toxins -- 21 Hydroxylamines and Hydrazines -- 22 Diazonium and Tetrazolium Compounds -- 23 Nitro Compounds and Nitrogen Heterocycles -- 24 Photochemistry -- 24.1 UV-generated Radicals -- 24.2 Radical Generation from Exogenous Photosensitisers -- 24.3 Other Photochemical Studies -- 25 Ischemia-Reperfusion Injury -- 25.1 Heart and Vasculature -- 25.2 Brain -- 25.3 Liver, Kidney and Other Organs -- 26 Radiation Dosimetry -- 27 Spin Trap Artifacts and Misassignments -- References -- Chapter 2 Time-resolved Electron Paramagnetic Resonance Studies in Organic Photochemistry -- 1 Introduction -- 2 The Mechanisms of CIDEP -- 3 Theoretical Developments -- 4 TREPR Experiments -- 4.1 The TR (CW) EPR Experiment -- 4.2 TREPR at Multiple Microwave Frequencies -- 4.3 Optically Detected Magnetic Resonance (ODMR) -- 4.3.1 RYDMR -- 4.3.2 FDMR -- 4.3.3 ADMR -- 4.4 Quantum Beats -- 4.5 Fourier Transform EPR -- 5 Applications in Organic Photochemistry -- 5.1 Fullerenes -- 5.2 Photosynthetic Model Systems -- 5.3 Radical Pairs in Micelles -- References
Chapter 3 Radiation Damage to DNA and Related Biomolecules -- 1 Introduction -- 1.1 Scope of this Report -- 1.2 Significance of the Field of Research -- 1.3 Symbols Used -- 2 DNA Constituents -- 2.1 Introduction -- 2.2 Pyrimidines -- 2.2.1 Single Crystal Studies -- 2.2.2 Frozen Aqueous Solutions and Glasses -- 2.3 Purines -- 2.3.1 Single Crystals -- 2.3.2 Glasses -- 2.4 Mixed Crystal Systems -- 2.5 Multi-base Investigations -- 2.5.1 Frozen Aqueous Solutions and Glasses -- 2.5.2 Peroxyl and Sulfoxyl Radicals -- 3 DNA, Polynucleotides and Oligonucleotides -- 3.1 Introduction -- 3.1.1 Symbols for DNA Radicals -- 3.1.2 The Direct, Quasi-direct and Indirect Effects -- 3.2 Radical Yields in DNA -- 3.2.1 Radical Distributions at Low Temperatures -- 3.2.2 Deconvolution of Complex Spectra: Important Confirmatory Results -- 3.2.3 Where are the Sugar Radicals in Irradiated DNA? -- 3.2.4 Evidence for Sugar Radicals in High LET Irradiated DNA -- 3.2.5 Recombination: An Important Fundamental Process in Radiation Damage to DNA -- 3.3 Radical Transfer in DNA -- 3.3.1 Electron Transfer Distances in DNA -- 3.3.2 Hole Transfer from the DNA Hydration Layer: Yields of Hydroxyl Radicals -- 3.4 DNA-Thiol Systems -- 3.5 Irreversible Protonation of Electron-gain Centers in DNA -- 3.6 Radiation Damage to DNA by Heavy-ion Beams -- 3.7 Spin Trapping of DNA Intermediates -- 3.8 New Techniques -- References -- Chapter 4 Spin-trapping: Recent Developments and Applications -- 1 Introduction -- 2 New Spin-traps -- 2.1 New Nitrones -- 2.2 New Isotopically-labelled Spin-traps -- 3 Applications in Organic Solvents -- 3.1 Spontaneous Formation of Spin Adducts -- 3.1.1 Inverted Spin-trapping -- 3.1.2 Other Mechanisms -- 3.2 Spin-trapping of Various Radicals -- 3.3 Miscellaneous -- 4 Applications in Aqueous Solutions -- 4.1 Superoxide -- 4.2 Hydroxyl Radical -- 5 Trapping of Nitric Oxide
6 Miscellaneous -- References -- Chapter 5 EPR and ENDOR Studies of Metalloproteins -- 1 Introduction -- 2 Copper -- 2.1 'Blue'Copper Sites -- 2.2 Type 2 Copper Sites -- 2.3 Binuclear Sites and Multi-centered Copper Proteins -- 3 Iron -- 3.1 Non-heme Iron Proteins -- 3.2 Heme-Iron Proteins -- 3.3 Iron-Sulfur Proteins -- 4 Nickel -- 5 Molybdenum and Tungsten -- 6 Vanadium -- 7 Manganese -- 8 Conclusions -- Acknowledgements -- References -- Chapter 6 Pulsed ESR of Microporous and Mesoporous Oxide Materials -- 1 Introduction -- 2 Organic Radicals -- 3 Transition Metal Ions -- 3.1 Cu(II) Systems -- 3.2 Ni(I) Systems -- 3.3 Pd(I) Systems -- 3.4 Fe(III) Systems -- 3.5 Mn(II) Systems -- 3.6 Ti(III) Systems -- 3.7 Cr(V), Mo(V) and V(IV) Systems -- 3.8 Paramagnetic Silver Clusters -- Acknowledgement -- References -- Chapter 7 Advanced EPR in Millimetre Bands and Very High Fields -- 1 Introduction -- 2 Techniques -- 3 Applications -- 3.1 Molecular Structure Studies -- 3.1.1 Single-electron Spin Systems -- 3.1.2 Multi-electron Spin Systems -- 3.2 Molecular Mobility Studies -- 4 High-field Low-temperature Effects -- 5 Conclusions -- Acknowledgments -- References -- Chapter 8 Electron Transfer Kinetics Studied by EPR/ESR and Related Methods -- 1 Introduction -- 2 Bibliography -- 3 Marcus Theory of Electron Transfer Reactions in Solution -- 4 Intermolecular Electron Transfer Rate Constants from EPR Measurements -- 4.1 Time-resolved EPR at Constant Magnetic Field -- 4.2 Dynamic ESR Line-broadening Measurements -- 4.2.1 Homogeneous Electron Self-exchange Reactions -- 4.2.2 Degenerate Intramolecular Electron Exchange Reactions -- 4.3 Electron Self-exchange Rates from Other Magnetic Resonance Methods -- 4.3.1 Fluorescence-detected Magnetic Resonance Measurements -- 4.3.2 Time-resolved CIDNP and CIDEP Measurements -- 4.3.3 FT-EPR Measurements
4.3.4 RYDMR and MARY Methods -- Acknowledgements -- References -- Author Index
Reflecting the growing volume of published work in this field, researchers will find this book an invaluable source of information on current methods and applications
Description based on publisher supplied metadata and other sources
Electronic reproduction. Ann Arbor, Michigan : ProQuest Ebook Central, 2020. Available via World Wide Web. Access may be limited to ProQuest Ebook Central affiliated libraries
鏈接 Print version: Sevilla, Michael D Electron Paramagnetic Resonance : Volume 16 Cambridge : Royal Society of Chemistry,c1998 9780854043057
主題 Electron paramagnetic resonance
Electronic books
Alt Author Becker, D
Huttermann, Juergen
Timmins, Graham S
Doubinski, A A
Forbes, Malcolm D E
Grampp, Gunther
Kevan, Larry
Hartmann, Martin
Tordo, Paul
Record:   Prev Next