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作者 Fihri, Aziz
書名 Aqueous Microwave Assisted Chemistry : Synthesis and Catalysis
出版項 Cambridge : Royal Society of Chemistry, 2010
©2010
國際標準書號 9781849730990 (electronic bk.)
9781849730389
book jacket
版本 1st ed
說明 1 online resource (243 pages)
text txt rdacontent
computer c rdamedia
online resource cr rdacarrier
系列 ISSN ; v.7
ISSN
附註 Aqueous Microwave Assisted Chemistry -- Contents -- About the Authors -- Chapter 1 Fundamentals of Aqueous Microwave Chemistry -- 1.1 Introduction -- 1.2 Green Chemistry Approach -- 1.3 Water as Green Solvent -- 1.4 Why Microwaves? -- 1.4.1 Thermal Effect -- 1.4.2 Non-thermal Effect -- 1.4.3 Selectivity towards Water -- 1.4.4 Selectivity towards Catalyst -- 1.4.5 Catalyst as Susceptors -- 1.4.6 Stability of Catalyst -- 1.5 Conclusion -- References -- Chapter 2 Metal-catalyzed Reactions in Water under MW Irradiation -- 2.1 Introduction -- 2.2 Addition Reactions -- 2.3 Isomerization Reactions -- 2.4 Substitution Reactions -- 2.5 Cyclization Reactions -- 2.6 Reduction and Oxidation Reactions -- 2.7 Miscellaneous Reactions -- 2.8 Representative Experimental Examples -- 2.8.1 Addition Reactions -- 2.8.2 Isomerization Reactions -- 2.8.3 Substitution Reactions -- 2.8.4 Cyclization Reactions -- 2.8.5 Reduction and Oxidation Reactions -- 2.8.6 Miscellaneous Reactions -- 2.9 Conclusions -- Acknowledgements -- References -- Chapter 3 Microwave-assisted Coupling Reactions in Aqueous Media -- 3.1 Introduction -- 3.2 Suzuki-Miyaura Reaction -- 3.3 Heck Reaction -- 3.4 Sonogashira Reactions -- 3.5 Stille Reactions -- 3.6 Hiyama Reactions -- 3.7 Cyanation Reactions -- 3.8 Carbonylation Reactions -- 3.9 Representative Experimental Syntheses -- 3.9.1 Synthesis of 4,5-Dimethoxy-2-vinyl-2'-pivaloylamino-biphenyl -- 3.9.2 Synthesis of 4-Phenyltoluene -- 3.9.3 Synthesis of m-Carboxycinnamic Acid in Homogeneous Heck Reactions in D2O -- 3.9.4 Synthesis of Ethyl 3-(6-Methoxy-2-naphthyl)propanoate -- 3.9.5 Synthesis of 5-Chloro-2-phenylethynylpyridine -- 3.9.6 Synthesis of 4-Methoxybenzonitrile -- 3.9.7 Aminocarbonylation and Hydroxycarbonylation -- 3.10 Conclusion -- References -- Chapter 4 Microwave-assisted Synthesis of Bio-active Heterocycles in Aqueous Media
4.1 Introduction -- 4.2 MW-assisted Nitrogen-containing Heterocycle Synthesis in Water -- 4.3 MW-assisted Synthesis of Oxygen- and Sulfur-containing Heterocycles in Water -- 4.4 MW-assisted Miscellaneous Reactions in Water -- 4.5 Representative Experimental Procedures -- 4.5.1 Synthesis of Dihydropyrimidinones -- 4.5.2 Synthesis of 2-Aminochromene Derivatives -- 4.5.3 Synthesis of Dioxane-functionalized Molecules -- 4.5.4 Synthesis of Sulfonyl-benzothiazole-based Bio-active Compounds -- 4.5.5 Synthesis of a Series of new β-Aminoketones -- 4.6 Conclusions -- References -- Chapter 5 Microwave-assisted Enzymatic Reactions in Aqueous Media -- 5.1 Introduction -- 5.2 Microwave-assisted Enzymatic Reactions in Water (or Aqueous Buffer) -- 5.2.1 Effect of Microwave Irradiation on Enzyme Activity in Aqueous Solutions -- 5.2.2 Microwave-assisted Enzymatic Protein Digestion -- 5.3 Microwave-assisted Enzymatic Reactions in Aqueous Solutions of Organic Solvents -- 5.4 Microwave-assisted Enzymatic Reactions in Ionic Liquids -- 5.5 Non-thermal Effect of Microwave Irradiation on Enzymes -- 5.6 Prospects of Microwave Irradiation in Aqueous Phase Biocatalysis -- 5.7 Experimental -- 5.7.1 Enzymatic Hydrolysis of Starch in Water under Microwave Irradiation -- 5.7.2 Enzymatic Transglycosylation of Lactose in Hexanol-Water (70 : 30, v/v) under Microwave -- 5.7.3 Enzymatic Digestion of Proteins (Cytochrome c, Myoglobin, Lysozyme, and Ubiquitin) -- Acknowledgements -- References -- Chapter 6 Microwave-assisted Synthesis of Polymers in Aqueous Media -- 6.1 Introduction -- 6.2 Radical Polymerization in Aqueous Medium -- 6.2.1 Free-Radical Polymerization -- 6.2.2 Radical Polymerization in Dispersed Media -- 6.2.3 Controlled/Living Radical Polymerization in Dispersed Media -- 6.3 Step-growth Polymerization in Aqueous Media -- 6.3.1 Synthesis of Poly(ether)s
6.3.2 Synthesis of Poly(amide)s and Poly(imide)s -- 6.3.3 Synthesis of Polytriazoles -- 6.3.4 C-C Coupling Polymerizations -- 6.4 Miscellaneous Polymer Synthesis in Aqueous Media -- 6.4.1 Cationic Polymerization -- 6.4.2 Polymer Modifications -- 6.4.3 Solid-phase Peptide Synthesis in Water -- 6.5 Experimental -- 6.5.1 PMMA Grafting onto a Polysaccharide -- 6.5.2 PMMA Synthesis in Emulsion Polymerization -- 6.5.3 Synthesis of PMMA Nanoparticles -- 6.5.4 Synthesis of Polyacrylamide-Calcium Phosphate Nanocomposites -- 6.5.5 Nitroxide-assisted Synthesis of Styrene in Miniemulsion -- 6.5.6 Synthesis of Poly(ether)s -- 6.5.7 Synthesis of Poly(imide)s -- 6.5.8 Polymerization by C-C Coupling -- 6.5.9 Cationic Polymerization -- 6.5.10 Polymer Modification by Click Chemistry -- References -- Chapter 7 Microwave-assisted Synthesis of Nanomaterials in Aqueous Media -- 7.1 Introduction -- 7.2 Synthesis of Metal Nanoparticles using Water under Microwave Irradiation -- 7.2.1 Gold (Au) Nanoparticles -- 7.2.2 Silver (Ag) Nanoparticles -- 7.2.3 Palladium (Pd) and Platinum (Pt) Nanoparticles -- 7.3 Synthesis of Metal Oxide Nanoparticles in Aqueous Medium under MW Irradiation Conditions -- 7.3.1 Synthesis of Titania (TiO2) Nanoparticles -- 7.3.2 Synthesis of ZnO Nanoparticles -- 7.3.3 Synthesis of Ferrite Nanoparticles -- 7.3.4 Synthesis of Quantum Dots in Aqueous Medium under Microwave Conditions -- 7.4 Nanoparticles as Catalysts -- 7.5 Ruthenium Hydroxide Nano-catalyst for Microwave-assisted Hydration of Nitriles in Water -- 7.6 Glutathione-based Nano-organocatalyst for Microwave-assisted Synthesis of Heterocycles in Water -- 7.7 Representative Experimental Procedures -- 7.7.1 Synthesis of Gold Nanoparticles -- 7.7.2 Synthesis of Silver Nanoparticles -- 7.7.3 Synthesis of Different TiO2 Nanoparticles -- 7.7.4 Synthesis of ZnO Nanostructures
7.7.5 Selected Methods for Production of Ferrite Nanoparticles -- 7.8 Conclusion -- References -- Subject Index
Provides a comprehensive overview of the various processes developed using aqueous microwave chemistry, which is an environmentally, friendly green chemistry technique
Description based on publisher supplied metadata and other sources
Electronic reproduction. Ann Arbor, Michigan : ProQuest Ebook Central, 2020. Available via World Wide Web. Access may be limited to ProQuest Ebook Central affiliated libraries
鏈接 Print version: Fihri, Aziz Aqueous Microwave Assisted Chemistry : Synthesis and Catalysis Cambridge : Royal Society of Chemistry,c2010 9781849730389
主題 Microwave heating
Electronic books
Alt Author Zhao, Hua
Cadierno, Victorio
Baruwati, Babita
Marestin, C
Polshettiwar, Vivek
Varma, Rajender S
Clark, James H
Kraus, George A
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